The Fifth Hokage of Konoha and the woman Jiraiya pursued all his life. If Jiraiya were to turn evil, Tsunade would be the first to stand up and stop him. She might even defeat him without using any chakra, leveraging Jiraiya's love for her to convince him to surrender.
The Third Hokage: Jiraiya respects his teacher immensely, so he would never accept a challenge from the Third Hokage.
Fugaku: The leader of the Uchiha clan who unlocked the Mangekyo Sharingan and possessed powerful Sharingan abilities. Although his specific abilities are not mentioned, it is clear that Jiraiya would have a hard time if he fell under Fugaku's genjutsu.
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